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Isomer & Cycloalkane Flipbook PDF
Isomer & Cycloalkane
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IUPAC Nomenclature of Cycloalkanes 1. In the case of a cycloalkane with an attached alkyl substituent, the ring is the parent hydrocarbon. 2. There is no need to number the position of a single substituent on a ring. 3. If the ring has two different substituents, they are cited in alphabetical order and the number 1 position is given to the substituent cited first.
Cycloalkanes CH2 H2C CH2
=
Cyclopropane
H2C H2C
CH2 CH
CH2 CH2
CH3 Methylcyclohexane
= CH3
Cycloalkanes CH2 H2C
CH CH2CH2CH2CH2CH2CH3 CH2 1-Cyclobutylhexane
(CH2)5CH3
or Hexylcyclobutane
Cycloalkanes H2C H2C
CH2 CH2
CH CH
CH2
CH3
6
=
CH3
1-Ethyl-2-methylcyclohexane
5 4
1
2 3
Name the Following Compounds
Isomerism
Isomerism – The phenomenon whereby certain chemical compounds have structures that are different although the compounds possess the same elemental composition.
Isomers – Two or more chemical substances having the same elementary composition and molecular weight but differing in structure.
Isomerism
Consider C4H10
These structures are constitutional
isomers
Isomerism
Consider C5H12
These structures are constitutional
isomers
Isomerism
Consider C6H14
These structures are constitutional
isomers