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Metal Primer - Reliance Orthodontic Products Flipbook PDF
Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regu
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 5/27/2015
Version: 8
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.
Product identifier
Product form
: Mixture
Product name
: Metal Primer
1.2.
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture 1.3.
: For professional use only.
Details of the supplier of the safety data sheet
Manufacturer: Reliance Orthodontic Products Inc. 1540 West Thorndale Ave. Itasca, IL 60143 USA 630-773-4009, during normal business hours 1.4.
Emergency telephone number
Emergency number
: 1-703-527-3887
SECTION 2: Hazards identification 2.1.
Classification of the substance or mixture
Classification (GHS-US) Flam. Liq. 2 Skin Irrit. 2 Skin Sens. 1 STOT SE 3 Aquatic Acute 3
H225 H315 H317 H335 H402
Full text of H-phrases: see section 16
2.2.
Label elements
GHS-US labeling Hazard pictograms (GHS-US)
:
Signal word (GHS-US)
: Warning
Hazard statements (GHS-US)
: H225 - Highly flammable liquid and vapor H315 - Causes skin irritation H317 - May cause an allergic skin reaction H335 - May cause respiratory irritation H402 - Harmful to aquatic life
Precautionary statements (GHS-US)
: P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 - Keep container tightly closed P264 - Wash hands thoroughly after handling P332+P313 - If skin irritation occurs: Get medical advice/attention P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose in a safe manner in accordance with local/national regulations.
GHS02
2.3.
GHS07
Other hazards
No additional information available 2.4.
Unknown acute toxicity (GHS-US)
Not applicable
SECTION 3: Composition/information on ingredients 3.1.
Substance
Not applicable EN (English US)
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
3.2.
Mixture
Name
Product identifier
%
Classification (GHS-US)
methylmethacrylate, monomer, inhibited
(CAS No) 80-62-6
>= 85
Flam. Liq. 2, H225 Skin Irrit. 2, H315 Skin Sens. 1, H317 STOT SE 3, H335 Aquatic Acute 3, H402
4-Methacryloxyethyl Trimellitc
(CAS No) 70293-55-9
1-5
Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335
Full text of H-phrases: see section 16
SECTION 4: First aid measures 4.1.
Description of first aid measures
First-aid measures general
: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation
: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell.
First-aid measures after skin contact
: Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). If skin irritation or rash occurs:
First-aid measures after eye contact
: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist.
First-aid measures after ingestion
: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
: May cause an allergic skin reaction. May cause respiratory irritation.
Symptoms/injuries after skin contact
: Causes skin irritation.
4.3.
Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures 5.1.
Extinguishing media
Suitable extinguishing media
: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media
: Do not use a heavy water stream.
5.2.
Special hazards arising from the substance or mixture
Fire hazard
: Highly flammable liquid and vapor.
Explosion hazard
: May form flammable/explosive vapor-air mixture.
5.3.
Advice for firefighters
Firefighting instructions
: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures 6.1.
Personal precautions, protective equipment and emergency procedures
General measures 6.1.1.
For non-emergency personnel
Emergency procedures 6.1.2.
: Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking.
: Evacuate unnecessary personnel.
For emergency responders
Protective equipment
: Equip cleanup crew with proper protection.
Emergency procedures
: Ventilate area.
6.2.
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 6.3.
Methods and material for containment and cleaning up
Methods for cleaning up
: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. EN (English US)
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
6.4.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage 7.1.
Precautions for safe handling
Additional hazards when processed
: Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling
: Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. Avoid breathing mist, vapors. Use only outdoors or in a well-ventilated area.
Hygiene measures
: Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Proper grounding procedures to avoid static electricity should be followed.
Storage conditions
: Keep in fireproof place. Keep container tightly closed.
Incompatible products
: Strong bases. strong acids.
Incompatible materials
: Sources of ignition. Direct sunlight. Heat sources.
7.3.
Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection 8.1.
Control parameters
Metal Primer ACGIH
Not applicable
OSHA
Not applicable
methylmethacrylate, monomer, inhibited (80-62-6) ACGIH ACGIH TWA (ppm)
50 ppm
ACGIH
ACGIH STEL (ppm)
50 ppm
OSHA
Not applicable
4-Methacryloxyethyl Trimellitc (70293-55-9) ACGIH Not applicable OSHA 8.2.
Not applicable Exposure controls
Personal protective equipment
: Avoid all unnecessary exposure.
Hand protection
: Wear protective gloves.
Eye protection
: Chemical goggles or safety glasses.
Skin and body protection
: Wear suitable protective clothing.
Respiratory protection
: Wear approved mask.
Other information
: When using, do not eat, drink or smoke.
SECTION 9: Physical and chemical properties 9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Color
: Light yellow.
Odor
: No data available
Odor threshold
: No data available
pH
: No data available
Relative evaporation rate (butyl acetate=1)
: No data available
Melting point
: No data available
Freezing point
: No data available
Boiling point
: No data available EN (English US)
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Flash point
: No data available
Auto-ignition temperature
: No data available
Decomposition temperature
: No data available
Flammability (solid, gas)
: No data available
Vapor pressure
: No data available
Relative vapor density at 20 °C
: No data available
Relative density
: No data available
Solubility
: Water: Solubility in water of component(s) of the mixture : • : 1.5 g/100ml
Log Pow
: No data available
Log Kow
: No data available
Viscosity, kinematic
: No data available
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidizing properties
: No data available
Explosive limits
: No data available
9.2.
Other information
No additional information available
SECTION 10: Stability and reactivity 10.1.
Reactivity
No additional information available 10.2.
Chemical stability
Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3.
Possibility of hazardous reactions
Not established. 10.4.
Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. 10.5.
Incompatible materials
strong acids. Strong bases. 10.6.
Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information 11.1.
Information on toxicological effects
Acute toxicity
: Not classified
methylmethacrylate, monomer, inhibited (80-62-6) LD50 oral rat > 6000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 7900 mg/kg bodyweight; Rat; Equivalent or similar to OECD 401; Weight of evidence; 8400 mg/kg bodyweight; Rat; Weight of evidence) LD50 dermal rabbit > 7550 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >5000 mg/kg bodyweight; Rabbit; Experimental value) LC50 inhalation rat (mg/l) 27.5 mg/l/4h (Rat; Literature study) ATE US (vapors) 27.500 mg/l/4h ATE US (dust, mist) 27.500 mg/l/4h Skin corrosion/irritation
: Causes skin irritation.
Serious eye damage/irritation
: Not classified
Respiratory or skin sensitization
: May cause an allergic skin reaction.
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
methylmethacrylate, monomer, inhibited (80-62-6) IARC group 3 - Not Classifiable EN (English US)
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
4-Methacryloxyethyl Trimellitc (70293-55-9) IARC group
4 - Probably Not Carcinogenic
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
: Not classified
Aspiration hazard
: Not classified
Potential Adverse human health effects and symptoms
: Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation
: May cause an allergic skin reaction. May cause respiratory irritation.
Symptoms/injuries after skin contact
: Causes skin irritation.
SECTION 12: Ecological information 12.1.
Toxicity
Ecology - water
: Harmful to aquatic life.
methylmethacrylate, monomer, inhibited (80-62-6) LC50 fish 1 130 mg/l (96 h; Pimephales promelas; Lethal) EC50 Daphnia 1 69 mg/l (48 h; Daphnia magna; GLP) LC50 fish 2 191 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 2 502 mg/l (24 h; Daphnia magna) TLM fish 1 159 mg/l (96 h; Pimephales promelas) Threshold limit other aquatic organisms 1 100 mg/l (16 h; Pseudomonas putida) Threshold limit algae 1 37 mg/l (168 h; Scenedesmus quadricauda; Toxicity test) Threshold limit algae 2 120 mg/l (192 h; Microcystis aeruginosa) 12.2.
Persistence and degradability
Metal Primer Persistence and degradability
Not established.
methylmethacrylate, monomer, inhibited (80-62-6) Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available. Photolysis in the air. Biochemical oxygen demand (BOD) 0.14 g O₂/g substance ThOD
1.9 g O₂/g substance
BOD (% of ThOD)
0.073 % ThOD
12.3.
Bioaccumulative potential
Metal Primer Bioaccumulative potential
Not established.
methylmethacrylate, monomer, inhibited (80-62-6) BCF fish 1 2.97 - 3.5 (Pisces) Log Pow 1.32 - 1.38 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method; 20 °C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4.
Mobility in soil
methylmethacrylate, monomer, inhibited (80-62-6) Surface tension 0.028 N/m (20 °C) 12.5.
Other adverse effects
Effect on ozone layer
:
Effect on the global warming
: No known ecological damage caused by this product.
Other information
: Avoid release to the environment. EN (English US)
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 13: Disposal considerations 13.1.
Waste treatment methods
Waste disposal recommendations
: Dispose in a safe manner in accordance with local/national regulations. Dispose in a safe manner in accordance with local/national regulations.
Additional information
: Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information In accordance with DOT Transport document description
: UN1247 Methyl methacrylate monomer, stabilized, 3, II
UN-No.(DOT)
: UN1247
Proper Shipping Name (DOT)
: Methyl methacrylate monomer, stabilized
Department of Transportation (DOT) Hazard Classes
: 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT)
: 3 - Flammable liquid
Packing group (DOT)
: II - Medium Danger
DOT Special Provisions (49 CFR 172.102)
: IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx)
: 150
DOT Packaging Non Bulk (49 CFR 173.xxx)
: 202
DOT Packaging Bulk (49 CFR 173.xxx)
: 242
DOT Quantity Limitations Passenger aircraft/rail : 5 L (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 : 60 L CFR 175.75) DOT Vessel Stowage Location
: B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.
DOT Vessel Stowage Other
: 40 - Stow ‘‘clear of living quarters’’
Additional information Other information
: No supplementary information available.
ADR Transport document description
: UN 1247, 3, II, (D/E)
Packing group (ADR)
: II
Class (ADR)
: 3 - Flammable liquid
Hazard identification number (Kemler No.)
: 339
Classification code (ADR)
: F1
Danger labels (ADR)
: 3 - Flammable liquids
EN (English US)
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Metal Primer Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Orange plates
:
Tunnel restriction code (ADR)
: D/E
LQ
: 1L
Excepted quantities (ADR)
: E2
Transport by sea No additional information available Air transport UN-No.(IATA)
: 1247
Class (IATA)
: 3 - Flammable Liquids
SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA No additional information available 4-Methacryloxyethyl Trimellitc (70293-55-9) WHMIS Classification
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Skin Irrit. 2 H315 Skin Sens. 1 H317 STOT SE 3 H335 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2.
National regulations
\ \
15.3. US State regulations
SECTION 16: Other information Other information
: None.
Full text of H-phrases: -----Aquatic Acute 3 -----Eye Irrit. 2A -----Flam. Liq. 2 -----Skin Irrit. 2 -----Skin Sens. 1 -----STOT SE 3 -----H225 -----H315 -----H317 -----H319 -----H335 -----H402
Hazardous to the aquatic environment - Acute Hazard Category 3 Serious eye damage/eye irritation Category 2A Flammable liquids Category 2 Skin corrosion/irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Highly flammable liquid and vapor Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation May cause respiratory irritation Harmful to aquatic life
SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
EN (English US)
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