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SDS no. J580 Version 6 Revision date 11/Jul/2017 Supersedes date 17/Jul/2015
Safety Data Sheet Water Gelling Agent J580 1. Identification 1.1 Product identifier Product name
Water Gelling Agent J580
Product code
J580
1.2 Relevant identified uses of the substance or mixture and uses advised against Recommended Use
Used as a fracturing additive in oilfield applications.
Uses advised against
Consumer use
1.3 Details of the supplier of the safety data sheet Supplier Schlumberger Technology Corporation 110 Schlumberger Drive Sugar Land, Texas 77478, USA Telephone: 1-281-285-7873
Schlumberger Canada, Ltd. 200, 125 - 9th Avenue SE Calgary, Alberta T2G 0P6, Canada Telephone: 1-613-992-4624
E-mail address [email protected] Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Thai Hien Nguyen 1.4 Emergency Telephone Number Emergency telephone (24 Hour) Asia Pacific +65 3158 1074, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, USA +1 281 595 3518/+1 866 928 0789 , Canada +1 800 579 7421 , Argentina: +54 11 5984 3690, Brazil : 0800-720-8000 /0800-777-2323 (WGRA)
2. Hazards identification 2.1 Classification of the substance or mixture GHS - Classification Health hazards
Not classified
Environmental hazards
Not classified
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Water Gelling Agent J580
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_____________________________________________________________________________________________ Physical Hazards Combustible dust
Category 1
2.2 Label elements
Signal word WARNING Hazard statements H232 - May form combustible dust concentrations in air Precautionary statements P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment P243 - Take precautionary measures against static discharge Hazards not otherwise classified None known Not applicable.
Unknown acute toxicity
3. Composition/information on Ingredients 3.1 Substances Chemical Name
CAS No
Weight-%
Carbohydrate polymer
Proprietary
60-100
3.2 Mixtures Not applicable
Comments Proprietary component(s) in section 3 of this SDS does not/do not trigger application of trade secret exemption under Hazardous Materials Information Review Act (HMIRA). The proprietary component in this product contributes to combustible dust classification.
4. First aid measures 4.1 First aid measures Inhalation
If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion
Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Seek medical attention if irritation occurs.
Skin contact
Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Seek medical attention if irritation occurs.
Eye Contact
Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
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_____________________________________________________________________________________________ 4.2. Most important symptoms and effects, both acute and delayed General advice
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms Inhalation
Please see Section 11. Toxicological Information for further information.
Ingestion
Please see Section 11. Toxicological Information for further information.
Skin contact
Please see Section 11. Toxicological Information for further information.
Eye contact
Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed Notes to physician
Treat symptomatically
5. Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Water Fog, Alcohol Foam, CO2, Dry Chemical. Extinguishing media which must not be used for safety reasons Do not use water jet. 5.2. Special hazards arising from the substance or mixture Unusual fire and explosion hazards Suspended dust may present a dust explosion hazard. Hazardous combustion products Thermal decomposition can lead to release of irritating gases and vapors. 5.3 Advice for firefighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus and full protective gear. Special Fire-Fighting Procedures Containers close to fire should be removed immediately or cooled with water.
6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Do not get on skin or clothing. Wash thoroughly after handling. Use personal protective equipment. See also section 8. 6.2 Environmental precautions The product should not be allowed to enter drains, water courses or the soil. Environmental exposure controls
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_____________________________________________________________________________________________ Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading. Methods for cleaning up Avoid dust formation. Do not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Take precautionary measures against static discharges. Use non-sparking tools and equipment. Material becomes slippery when wet. Use caution if wet. After cleaning, flush away traces with water. 6.4 Reference to other sections See section 13 for more information.
7. Handling and storage 7.1 Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid handling causing generation of dust. Material becomes slippery when wet. Use caution if wet. Avoid breathing dust; if exposed to high dust concentration, leave area immediately. Fine dust dispersed in air may ignite. Take precautionary measures against static discharges. Hygiene measures Use good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product. Wash hands and face before breaks and immediately after handling the product. 7.2 Conditions for safe storage, including any incompatibilities Technical measures/precautions
Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dust is formed. Keep airborne concentrations below exposure limits.
Storage precautions
Keep away from open flames, hot surfaces and sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated place.
8. Exposure controls/personal protection 8.1 Control parameters Exposure limits
Component Carbohydrate polymer ( 60-100 )
Control as an ACGIH particulate not otherwise specified (PNOS): 10 mg/m3 (Inhalable); 3 mg/m3 (Respirable) and an OSHA particulate not otherwise regulated (PNOR): 15 mg/m3 (Total); 5 mg/m3 (Respirable).
ACGIH TLV Not determined
OSHA PEL Not determined
8.2 Exposure controls A risk assessment is recommended to be performed by a qualified and trained personnel to analyze the worksite and recommends the appropriate controls such as engineering controls, work practice controls, and administrative controls as primary means of reducing employee exposure. When there is a remaining hazards after applying the primary controls, Personal Protective Equipment (PPE) must be used.
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_____________________________________________________________________________________________ All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation. Engineering Controls Ensure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipment Eye protection Hand protection Respiratory Protection
Skin and body protection Hygiene Measures
Tightly fitting safety goggles. Wear chemical resistant gloves such as nitrile or neoprene. Frequent change is advisable All respiratory protection equipment should be used within a comprehensive respiratory protection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHA Respiratory Protection Standard) or local equivalent.If exposed to airborne mist/aerosol of this product, use an organic vapor cartridge with a P-95 pre-filter attached. In work environments containing oil mist/aerosol, use an organic vapor cartridge with a P-95 pre-filter attached.If exposed to vapors from this product, use a NIOSH/MSHA-approved respirator with an organic vapor cartridge. Wear suitable protective clothing, Eye wash and emergency shower must be available at the work place. Wash hands before breaks and immediately after handling the product, Remove and wash contaminated clothing before re-use.
9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Solid Physical state Powder Appearance Light tan Color Slight Odor Not applicable Odor threshold Property pH pH @ dilution Melting / freezing point
Values No information available 5.5 - 7.5 > 180°C/ 356°F
Boiling point/range Flash point Evaporation rate (BuAc =1) Flammability (solid, gas) Flammability Limit in Air Upper flammability limit Lower flammability limit Vapor pressure Vapor density Specific gravity Bulk density Water solubility Solubility in other solvents Autoignition temperature Decomposition temperature
No information available No information available No information available Not applicable No information available No information available No information available No information available 1.40 - 1.45 g/cm3 800 kg/m3 Dispersible No information available No information available > 242°C/ 468°F
Kinematic viscosity Dynamic viscosity
No information available No information available
Remarks @ 10 g/l
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_____________________________________________________________________________________________ log Pow
No information available
Explosive properties Oxidizing properties
Suspended dust may present a dust explosion hazard None known.
9.2 Other information Pour point Molecular weight VOC content(%) Density
No information available No information available No information available No information available
Comments The data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and reactivity 10.1 Reactivity No specific reactivity hazards associated with this product. 10.2 Chemical stability Stable under normal temperature conditions and recommended use. 10.3 Possibility of Hazardous Reactions Hazardous polymerization Hazardous polymerization does not occur. 10.4 Conditions to avoid Avoid dust formation. Avoid heat, flames and other sources of ignition. 10.5 Incompatible materials Strong oxidizing agents. 10.6 Hazardous decomposition products See Section 5.2.
11. Toxicological information 11.1 Information on toxicological effects
Acute toxicity Inhalation
Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and cough.
Eye contact
Dust may cause mechanical irritation.
Skin contact
Repeated exposure may cause skin dryness or cracking.
Ingestion
Ingestion may cause stomach discomfort.
Chemical Name Carbohydrate polymer
LD50 Oral = 6770 mg/kg ( Rat )
LD50 Dermal No data available
LC50 Inhalation No data available
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Chemical Name Carbohydrate polymer
IARC Group 1 or 2 No data available
ACGIH - Carcinogens No data available
OSHA listed carcinogens No data available
NTP No data available
Sensitization
Not classified.
Mutagenic effects
This product does not contain any known or suspected mutagens.
Carcinogenicity
This product does not contain any known or suspected carcinogens.
Reproductive toxicity
This product does not contain any known or suspected reproductive hazards.
Developmental toxicity
Not known to cause birth defects or have a deleterious effect on a developing fetus.
Routes of exposure
Inhalation. Skin contact. Eye contact.
Routes of entry
Inhalation.
Specific target organ toxicity Single exposure Specific target organ toxicity Repeated exposure
Not classified
Aspiration hazard
Not applicable.
Not classified.
12. Ecological information 12.1 Toxicity Toxicity to algae No product level data available. Toxicity to fish No product level data available. Toxicity to daphnia and other aquatic invertebrates No product level data available. Chemical Name Carbohydrate polymer
Toxicity to fish
Toxicity to algae
No information available
No information available
Toxicity to daphnia and other aquatic invertebrates No information available
12.2 Persistence and degradability No information available. 12.3 Bioaccumulative potential No information available. 12.4 Mobility in soil
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_____________________________________________________________________________________________ No information available. 12.5 Results of PBT and vPvB assessment This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT) This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB) 12.6 Other adverse effects. None known. Check for additional information in sect. 7.
13. Disposal considerations 13.1 Waste treatment methods Disposal Method
Disposal should be made in accordance with federal, state and local regulations.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information 14.1. UN number UN No. (DOT) UN No. (TDG) UN/ID No. (ADR/RID/ADN/ADG) UN No. (IMDG) UN No. (ICAO)
Not regulated Not regulated Not regulated Not regulated Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods 14.3 Hazard class(es) DOT Hazard class TDG Hazard class ADR/RID/ADN/ADG Hazard class IMDG Hazard class ICAO Hazard class/division
Not regulated Not regulated Not regulated Not regulated Not regulated
14.4 Packing group DOT Packing group TDG Packing group ADR/RID/ADN/ADG Packing group IMDG Packing group ICAO Packing group
Not regulated Not regulated Not regulated Not regulated Not regulated
14.5 Environmental hazard Marine pollutant
No
14.6 Special precautions None
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15. Regulatory information International inventories Complies Complies Complies Complies Complies Complies Complies Complies
USA (TSCA) Canada (DSL) Philippines (PICCS) Japan (ENCS) China (IECSC) Australia (AICS) Korean (KECL) New Zealand (NZIoC)
Europe - REACH All products supplied from the European Economic Area (EEA) are compliant with the REACH Regulation EC 1907/2006.For products supplied from the EEA, Schlumberger and/or its suppliers have pre-registered and is registering all of the substances that it and/or its suppliers manufactures in or imports into the EEA that are subject to Title II of the REACH Regulation. All products supplied from outside the EEA are subject to REACH only if imported into the EEA. The importer of the products must comply with REACH for each imported substance. Contact [email protected] for REACH information. IMPORTS, Canada No import volume restrictions. U.S. Federal and State Regulations SARA 311/312 Hazard Categories Fire Hazard (Combustible Dust)
Chemical Name Carbohydrate polymer
SARA 302 / TPQs N/A
SARA 313 N/A
CERCLA RQ N/A
State Comments Proposition 65: This product is not known to contain chemicals considered by the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer and/or reproductive toxicity at levels that are expected to pose a significant risk under anticipated use conditions. Canadian Classification This Safety Data Sheet has been prepared in compliance with the Hazardous Products Regulations.
16. Other information Supersedes date
17/Jul/2015
Revision date
11/Jul/2017
Version
6
This SDS has been revised in the
All sections. Updated according to WHMIS 2015.
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_____________________________________________________________________________________________ following section(s) HMIS classification Health Flammability Physical hazard
1 1 0
PPE
E
N/A - Not Applicable, N/D - Not Determined.
Disclaimer The information contained herein is considered in good faith as reliable of the date issued and is based upon on measur ement s,t est sordat ader i vedf r om suppl i er ’ sownst udyorf ur ni shedby ot her s.I npr ovi di ngt hi sSDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maxi mum ext entper mi t t edbyl aw,suppl i er ’ swar r ant yobl i gat i onsandbuyer ’ ssol er emedi esar easst at edi nsepar at e agreement between the parties.
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